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Hence, if the intrinsic defect states were degrading the device, a decrease in the photocurrent should have been observed almost instantaneously after photoexcitation contrary to the slow degradation observed over hours. This is consistent with our observation of a pure bi molecular recombination process, which is a signature of low defect density in the large grain size perovskites observed during normal solar cell operation and also in the time resolved PL measurements24,25. Furthermore recent work by Tian et al.26,27 reported relatively slow timescale (mins) PL enhancement in MAPbI3 thin film under continuous light illumination and in different environments.